STATE WATER RESOURCES CONTROL BOARD MEETING

BOARD MEETING SESSION --DIVISION OF WATER QUALITY

SEPTEMBER 2, 1998

ITEM: 3

SUBJECT: CONSIDERATION OF A RESOLUTION TO ADOPT A WATER QUALITY CONTROL POLICY FOR GUIDANCE ON DEVELOPMENT OF REGIONAL TOXIC HOT SPOT CLEANUP PLANS

DISCUSSION: The State Water Resources Control Board (SWRCB) and the Regional Water Quality Control Boards, as part of the Bay Protection and Toxic Cleanup Program, are required by Water Code Section 13394 to develop Regional Toxic Hot Spot Cleanup Plans and subsequently a consolidated Statewide Toxic Hot Spot Cleanup Plan for submission to the Legislature by June 30, 1999. In order to accomplish this, the SWRCB staff has prepared a draft Water Quality Control Policy (Policy) that establishes guidance for the consistent development of the regional cleanup plans. The proposed Policy contains a specific definition of a toxic hot spot, a list of general criteria for assessment and priority ranking of toxic hot spots, as well as other factors needed for the consistent development of the cleanup plans.

SWRCB staff has prepared a final Functional Equivalent Document (FED) for the proposed Policy in compliance with the California Environmental Quality Act. The FED contains an analysis of the environmental issues and alternatives to be considered by the SWRCB in adopting the Policy. On May 5, 1998 and on May 11, 1998 the SWRCB held public hearings seeking comments regarding the proposed Policy. Public comments and staff responses have been summarized and incorporated into the FED. In compliance with Health and Safety Code Section 57004, the draft FED was peer reviewed by scientists at the University of California. The results of the peer review have been incorporated into the final FED.

As directed at the July 8, 1998 Board Meeting, staff met with the Department of Pesticide Regulation staff to discuss the definition of "accumulated" and other concerns. Several consensus points were discussed, and the FED has been revised to address some of these concerns.

POLICY ISSUE: Should the SWRCB adopt the proposed Water Quality Control Policy for the Guidance on Development of Regional Toxic Hot Spot Cleanup Plans?

FISCAL IMPACT: This is a budgeted activity. It is the first of a three-step adoption process that will culminate in the submission of a consolidated Statewide Toxic Hot Spot Cleanup Plan to the Legislature by June 30, 1999.

RWQCB IMPACT: Yes. North Coast, San Francisco Bay, Central Valley, Central Coast, Los Angeles, Santa Ana, and San Diego Regional Water Quality Control Boards.

STAFF RECOMMENDATION: That the SWRCB adopt the proposed Water Quality Control Policy for Guidance on Development of Regional Toxic Hot Spot Cleanup Plans.


AUGUST 21,1998 DRAFT

STATE WATER RESOURCES CONTROL BOARD

RESOLUTION NO. 98-

ADOPTION OF THE WATER QUALITY CONTROL POLICY FOR GUIDANCE ON DEVELOPMENT OF REGIONAL TOXIC HOT SPOT CLEANUP PLANS

WHEREAS:

1. The Bay Protection and Toxic Cleanup Program (BPTCP) was established by the State Water Resources Control Board (SWRCB) to implement the requirements of Section 13390 et seq. of the Water Code.

2. Water Code Section 13394 requires the SWRCB and the Regional Water Quality Control Boards (RWQCBs) to develop regional and consolidated statewide toxic hot spot cleanup plans.

3. To facilitate the consistent development of the regional toxic hot spot cleanup plans, a Water Quality Control Policy (Policy) has been developed pursuant to Water Code Section 13140 for guidance on the development of regional toxic hot spot cleanup plans.

4. The SWRCB prepared and circulated a draft Functional Equivalent Document (FED) supporting the proposed Policy in accordance with provisions of the California Environmental Quality Act and Title 14, California Code of Regulations Section 15251(g).

5. In compliance with Water Code Section 13147, the SWRCB held public hearings in Newport Beach, California on May 5, 1998 and in Sacramento, California on May 11, 1998 on the Policy and has carefully considered all testimony and comments received.

6. The SWRCB determined that the adoption of the proposed Policy will not have a significant adverse effect on the environment.

7. The SWRCB staff has prepared a final FED which includes the proposed Policy and responses to the comments received.

8. The SWRCB consulted with the Department of Fish and Game (DFG) on the potential impacts of the amendments on fish and wildlife resources, including threatened and endangered species. DFG found that adoption of the proposed Policy will not jeopardize the continued existence of any endangered or threatened species, or result in the destruction or adverse modification of habitat essential to the continued existence of the species. The adoption of the policy will not result in the taking of any endangered or threatened species incidental to the proposed Policy.

9. The SWRCB has consulted with DFG and the Office of Environmental Health Hazard Assessment on the development of criteria to rank toxic hot spots.

10. The SWRCB has completed a scientific peer review by University of California scientists of the draft FED as required by Section 57004 of the Health and Safety Code.

11. The regulatory provisions of the Policy do not become effective until the regulatory provisions are approved by the Office of Administrative Law (OAL).

THEREFORE BE IT RESOLVED THAT:

The SWRCB:

1. Approves the final FED: Water Quality Control Policy for Guidance on the Development of Regional Toxic Hot Spot Cleanup Plans.

2. Adopts the Water Quality Control Policy for Guidance on Development of Regional Toxic Hot Spot Cleanup Plans (attached).

3. Will continue to consult with DFG on compliance with the California Endangered Species Act during the development of the Regional and Consolidated Toxic Hot Spot Cleanup Plans.

4. Intends that, with respect to registered pesticides, any actions of the SWRCB and the RWQCBs related to the development of cleanup plans shall be consistent with the Management Agency Agreement between the SWRCB and DPR.

5. Authorizes the Executive Director or his designee to submit the Water Quality Control Policy to OAL for their approval.

CERTIFICATION

The undersigned, Administrative Assistant to the Board, does hereby certify that the foregoing is a full, true, and correct copy of a resolution duly and regularly adopted at a meeting of the State Water Resources Control Board held on September 2, 1998.

Maureen Marché

Administrative Assistant to the Board


DRAFT AUGUST 21, 1998

STATE WATER RESOURCES CONTROL BOARD

WATER QUALITY CONTROL POLICY FOR GUIDANCE ON DEVELOPMENT OF REGIONAL TOXIC HOT SPOT CLEANUP PLANS

INTRODUCTION

The State Water Resources Control Board (SWRCB) and the Regional Water Quality Control Boards (RWQCBs) are mandated to identify toxic hot spots in the enclosed bays and estuaries of each of the seven coastal regions of the State (California Water Code Chapter 5.6, Section 13390 et seq.). The coastal RWQCBs are mandated to develop Regional Toxic Hot Spot Cleanup Plans specifying where and how each identified toxic hot spot will be remediated.

The Water Quality Control Policy for Guidance on Development of Regional Toxic Hot Spot Cleanup Plans is intended to provide guidance on the development of the Regional cleanup plans. The Policy contains a specific definition of a toxic hot spot, general ranking criteria, the mandatory contents of the cleanup plans, and issues to be considered by the SWRCB in the development of the consolidated toxic hot spot cleanup plan. The principles contained in this Policy apply to all enclosed bays, estuaries and coastal waters.

RWQCBs shall prepare their regional toxic hot spot cleanup plans in accordance with this Policy. Any site-specific variance from the Policy shall be approved by the SWRCB Executive Director.

CONTENTS OF REGIONAL TOXIC HOT SPOT CLEANUP PLANS

The Regional Toxic Hot Spot Cleanup Plans shall contain (at a minimum) the following information:

1. Introduction

The Introduction shall contain an identification of the Region. In general terms, the Bay Protection and Toxic Cleanup Program (BPTCP) goals (Chapter 5.6 of the California Water Code), authority and requirements to develop cleanup plans (Water Code Section 13394) shall be presented.

2. Toxic Hot Spot Definition

The Regional cleanup plans shall then present the specific definition of a Toxic Hot Spot (THS) presented in this Policy.

3. General Criteria For Ranking Toxic Hot Spots

The Water Code requirements for ranking criteria and the ranking criteria in this Policy shall be presented.

4. Monitoring Approach

The BPTCP has used effects-based measurements of impacts using the sediment quality triad (sediment toxicity, benthic community structure and measures of chemical concentrations in sediments) to identify toxic hot spots in California enclosed bays and estuaries. The BPTCP has used these measures in a two-step process. The first step is to screen sites using toxicity tests, benthic community structure, or measures of chemicals in sediments or tissues. In the second step, the highest priority sites with a response in any of the measures are retested to confirm the observed response.

The description of the monitoring approach shall be presented in the cleanup plan. If there are Region-specific modifications of the approach the modifications shall be briefly described.

5. A priority ranking of all THS (including a description of each THS including a characterization of the pollutants present at the site).

The RWQCBs shall use the definition of a candidate and known toxic hot spot listed in this Policy to identify toxic hot spots. The RWQCBs shall then rank sites using the Ranking Criteria in this Policy. The RWQCBs shall create one list of candidate toxic hot spots and rank the list using a matrix of the ranking criteria. For the Regional Toxic Hot Spot Cleanup Plans, areas of concern and other sites where information are unavailable shall not be ranked. RWQCBs may list sites that do not meet the definition of a toxic hot spot in a separate section under "Areas of Concern." Areas of Concern are sites with insufficient information available to declare as a candidate or known toxic hot spots.

For each candidate toxic hot spot listed in the Regional Toxic Hot Spot Cleanup Plan the following information shall be presented for each toxic hot spot:

A. Water body name. The name shall conform to the water body name in the RWQCB Basin Plan.

B. Segment Name. The RWQCBs shall list a descriptive name in the water body segment where the toxic hot spot is located if the segment name is more descriptive than the water body name.

C. Site Identification. The RWQCBs shall list a station or site identifier that can be linked to a monitoring station location (e.g., BPTCP monitoring station, State Mussel Watch station, discharger self monitoring station, or any other appropriate identifier).

D. Reason for Listing. The RWQCBs shall list the reason for the site or station to be listed. The value given shall be the appropriate trigger value(s) in the definition of a Toxic Hot Spot that is (are) the cause for the listing.

E. Pollutants present at the site. The RWQCBs shall also list which chemicals are present at sufficiently high levels to be of concern.

F. Report reference substantiating toxic hot spot listing. All references supporting the designation of the toxic hot spot shall be listed with the other information required for designation of a toxic hot spot. The references shall include, but not be limited to: author, year of publication, title of report, and other identifying information [e.g., name of journal (including volume and pages), RWQCB file number, agency report, or other identifier that will allow the report to be independently located].

6. Each candidate toxic hot spot with a "High" priority ranking shall be listed separately and the following information compiled for the site by the RWQCBs:

A. An assessment of the areal extent of the toxic hot spots.

The RWQCB shall characterize the areal extent of the toxic hot spot. For the proposed cleanup plans, the RWQCB shall estimate the boundary, size and/or volume of the toxic hot spot. In determining the areal extent the RWQCB shall consider a temporal component (i.e., the historic versus ongoing nature of the toxic hot spot) and the mix of chemicals present as well as any available information on toxicity and benthic community composition that would assist in characterizing the areal extent of the toxic hot spot. When considering sediments, the RWQCB shall consider the volumes to be addressed and depth of polluted sediments present at the site.

B. An assessment of the most likely sources of pollutants (potential dischargers).

RWQCBs shall list potential dischargers that are likely to have discharged or deposited the pollutants identified in the toxic hot spot lists.

Potential discharger identification shall be dependent on factors such as, site location, pollutant type, mix of chemicals found to be present at the site, and identification and location of the potential discharger.

In some cases, after a site is identified as a toxic hot spot, there may not be any identified potential discharger to assume the responsibility of cleanup. In such cases the identified toxic hot spot would remain reported as a toxic hot spot in the cleanup plan lists. The RWQCB and the SWRCB would assume the role of leadership to initiate cleanup through the adoption of the Consolidated Statewide Toxic Hot Spot Cleanup Plan.

C. A summary of actions that have been initiated by the RWQCBs to reduce the accumulation of pollutants at existing THSs and to prevent the creation of new THSs.

The summary of actions shall contain descriptions of any issued waste discharge requirements, National Pollutant Discharge Elimination System (NPDES) permits, general permits (e.g., construction, industrial stormwater, etc.), cleanup and abatement orders, cease and desist orders, administrative civil liability orders, actions taken or initiated by other State or Federal agencies (e.g., Department of Defense Base Closure, Damage Assessment activities of the National Oceanic and Atmospheric Administration, etc.), or any other actions.

D. Preliminary assessment of actions required to remedy or restore a THS including recommendations for remedial actions.

The RWQCBs shall evaluate the alternatives listed in the Remediation Methods section of this Policy. After evaluating the remediation alternatives the RWQCBs shall list their assessment of the actions that could be implemented.

In developing this preliminary list of actions the RWQCBs shall list, to the extent possible, potential environmental impacts of the proposed actions (either in the plan or in a separate report). These impacts could include, but are not limited to: impacts of sediment disposal, secondary impacts of dredging, disposal, pollutant releases from capped sites, pollutant releases from disposal facilities (both aquatic and upland), pollutant release during treatment or as a by-product of treatment (gaseous, solid and liquid), potential impacts of constructing new facilities to treat effluents, sludge disposal, possible air quality impacts, alterations in sewer systems, etc.

During implementation of the consolidated cleanup plan, the RWQCBs shall work with responsible parties to determine the appropriate and reasonable cleanup or remediation level.

E. An estimate of the total cost to implement the cleanup plan.

RWQCBs shall estimate costs of cleanup plan implementation using the estimates provided in this Policy or other referenced source. RWQCBs may deviate from the cost estimate in this Policy if justified in writing in the cleanup plan. If a potential discharger has been identified, the RWQCB shall require in the cleanup plan that the discharger prepare a proposal for site remedial actions. The proposal for site remediation shall include, but not be limited to, assessment of the areal extent of the toxic hot spot, cleanup actions and monitoring to assess effectiveness of any implemented cleanup actions. The RWQCB will also present a list of benefits (consistent with the guidance in this Policy) derived by implementing the cleanup plan.

F. An estimate of recoverable costs from potential dischargers.

The costs recoverable from potential dischargers shall be developed by the RWQCBs, if possible. The costs shall be justified in the cleanup plan.

G. A two-year expenditure schedule identifying funds to implement the plans that are not recoverable from potential dischargers.

The RWQCBs shall develop a brief workplan for the implementation of the cleanup plans for sites without potential dischargers identified. The workplan shall contain costs and estimated schedule for: finding polluted sediments or water (monitoring), assessment of areal extent of the toxic hot spot, implementation of remedial actions including, but not limited to, sediment removal and disposal, treatment of removed sediments, capping of polluted sediments, possible changes in WDRs, suggestions for improvements in wastewater discharge, or recommendations for implementing watershed management approaches. The expenditure plan shall also contain a funding proposal for assessing the effectiveness of remediation.

SPECIFIC DEFINITION OF A TOXIC HOT SPOT

The following specific definition provides a mechanism for identifying and distinguishing between "candidate" and "known" toxic hot spots. A candidate toxic hot spot is considered to have enough information to designate a site as a known toxic hot spot except that the candidate hot spot has not been approved by the RWQCB and the SWRCB. Once a candidate toxic hot spot has been adopted into the consolidated statewide toxic hot spot cleanup plan then the site shall be considered a known toxic hot spot and all the requirements of the Water Code shall apply to that site.

Candidate and known toxic hot spots are locations (sites in waters of the State) in enclosed bays, estuaries or the ocean. Dischargers (e.g. publicly owned treatment works, industrial facilities, power generating facilities, agricultural land, storm drains, etc.) are not toxic hot spots.

Candidate Toxic Hot Spot

A site meeting any one or more of the following conditions is considered to be a "candidate" toxic hot spot.

1. The site exceeds water or sediment quality objectives for toxic pollutants that are contained in appropriate water quality control plans or exceeds water quality criteria promulgated by the U.S. Environmental Protection Agency (U.S. EPA).

This finding requires chemical measurement of water or sediment, or measurement of toxicity using tests and objectives stipulated in water quality control plans. Determination of a toxic hot spot using this finding should rely on recurrent measures over time (at least two separate sampling dates). Suitable time intervals between measurements must be determined.

2. The water or sediment exhibits toxicity associated with toxic pollutants that is significantly different from the toxicity observed at reference sites (i.e., when compared to the lower confidence interval of the reference envelope or, in the absence of a reference envelope, is significantly toxic as compared to controls (using a t-test) and the response is less than 90 percent of the minimum significant difference for each specific test organism ), based on toxicity tests acceptable to the SWRCB or the RWQCBs.

To determine whether toxicity exists, recurrent measurements (at least two separate sampling dates) should demonstrate an effect. Appropriate reference and control measures must be included in the toxicity testing. The methods acceptable to and used by the BPTCP may include some toxicity test protocols not referenced in water quality control plans (e.g., the BPTCP Quality Assurance Project Plan). Toxic pollutants should be present in the media at concentrations sufficient to cause or contribute to toxic responses in order to satisfy this condition.

3. The tissue toxic pollutant levels of organisms collected from the site exceed levels established by the United States Food and Drug Administration (FDA) for the protection of human health, or the National Academy of Sciences (NAS) for the protection of human health or wildlife. When a health advisory against the consumption of edible resident non-migratory organisms has been issued by Office of Environmental Health Hazard Assessment (OEHHA) or Department of Health Services (DHS), on a site or water body, the site or water body is automatically classified a "candidate" toxic hot spot if the chemical contaminant is associated with sediment or water at the site or water body.

Acceptable tissue concentrations are measured either as muscle tissue (preferred) or whole body residues. Residues in liver tissue alone are not considered a suitable measure for candidate toxic hot spot designation. Animals can either be deployed (if a resident species) or collected from resident populations. Recurrent measurements in tissue are required. Residue levels established for one species for the protection of human health can be applied to any other consumable species.

Shellfish: Except for existing information, each sampling episode should include a minimum of three replicates. The value of interest is the average value of the three replicates. Each replicate should be comprised of at least 15 individuals. For existing State Mussel Watch information related to organic pollutants, a single composite sample (20-100 individuals), may be used instead of the replicate measures. When recurrent measurements exceed one of the levels referred to above, the site is considered a candidate toxic hot spot.

Fin-fish: A minimum of three replicates is necessary. The number of individuals needed will depend on the size and availability of the animals collected; although a minimum of five animals per replicate is recommended. The value of interest is the average of the three replicates. Animals of similar age and reproductive stage should be used.

4. Impairment measured in the environment is associated with toxic pollutants found in resident individuals.

Impairment means reduction in growth, reduction in reproductive capacity, abnormal development, histopathological abnormalities. Each of these measures must be made in comparison to a reference condition where the endpoint is measured in the same species and tissue is collected from an unpolluted reference site. Each of the tests shall be acceptable to the SWRCB or the RWQCBs.

Growth Measures: Reductions in growth can be addressed using suitable bioassay acceptable to the SWRCB or RWQCBs or through measurements of field populations.

Reproductive Measures: Reproductive measures must clearly indicate reductions in viability of eggs or offspring, or reductions in fecundity. Suitable measures include: pollutant concentrations in tissue, sediment, or water which have been demonstrated in laboratory tests to cause reproductive impairment, or significant differences in viability or development of eggs between reference and test sites.

Abnormal Development: Abnormal development can be determined using measures of physical or behavioral disorders or aberrations. Evidence that the disorder can be caused by toxic pollutants, in whole or in part, must be available.

Histopathology: Abnormalities representing distinct adverse effects, such as carcinomas or tissue necrosis, must be evident. Evidence that toxic pollutants are capable of causing or contributing to the disease condition must also be available.

5. Significant degradation in biological populations and/or communities associated with the presence of elevated levels of toxic pollutants.

This condition requires that the diminished numbers of species or individuals of a single species (when compared to a reference site) are associated with concentrations of toxic pollutants. The analysis should rely on measurements from multiple stations. Care should be taken to ensure that at least one site is not degraded so that a suitable comparison can be made.

Known Toxic Hot Spot

A site meeting any one or more of the conditions necessary for the designation of a "candidate" toxic hot spot that has gone through a full SWRCB and RWQCB hearing process, is considered to be a "known" toxic hot spot. A site will be considered a "candidate" toxic hot spot until approved by the SWRCB as a "known" toxic hot spot in the consolidated toxic hot spot cleanup plan.

RANKING CRITERIA

A value for each criterion described below shall be developed provided appropriate information exists or estimates can be made. Any criterion for which no information exists shall be assigned a value of "No Action". The RWQCB shall create a matrix of the scores of the ranking criteria. The RWQCBs shall determine which sites are "High" priority based on the five general criteria (below) keeping in mind the value of the water body. The RWQCBs shall provide the justification or reason a rank was assigned if the value is an estimate based on best professional judgment.

Human Health Impacts

Human Health Advisory issued for consumption of non-migratory aquatic life from the site (assign a "High"); Tissue residues in aquatic organisms exceed FDA/DHS action level or U.S. EPA screening levels ("Moderate").

Aquatic Life Impacts

For aquatic life, site ranking shall be based on an analysis of the preponderance of substantial information available (i.e., weight-of-evidence). The measures that shall be considered are: sediment chemistry, sediment toxicity, biological field assessments (including benthic community analysis), water toxicity, toxicity identification evaluations (TIEs), and bioaccumulation.

Stations with hits in any two of the biological measures if associated with high chemistry, assign a "High" priority. A hit in one of the measures associated with high chemistry is assigned "moderate", and high sediment or water chemistry only shall be assigned "low". In analyzing the preponderance of substantial information available, RWQCBs should take into consideration that impacts related to biological field assessments (including benthic community structure) are of more importance than other measures of impact.

Water Quality Objectives Footnote1

Any chemistry data used for ranking under this section shall be no more than 10 years old, and shall have been analyzed with appropriate analytical methods and quality assurance.

Water quality objective or water quality criterion: Exceeded regularly (assign a "High" priority), occasionally exceeded ("Moderate"), infrequently exceeded ("Low").

Areal Extent of Toxic Hot Spot

Select one of the following values: More than 10 acres, 1 to 10 acres, less than 1 acre.

Natural Remediation Potential

Select one of the following values: Site is unlikely to improve without intervention ("High"), site may or may not improve without intervention ("Moderate"), site is likely to improve without intervention ("Low").

Overall Ranking

The RWQCB shall list the overall ranking for the candidate toxic hot spot. Based on the interpretation and analysis of the five previous ranking criteria, ranks shall be established by the RWQCBs as "high", "moderate" or "low."

TABLE 1: NAS, FDA, AND U.S. EPA LIMITS RELEVANT TO THE BPTCP (NG/G WET WEIGHT)


Chemical

NAS Recommended Guideline Footnote2 (whole fish) FDA Action Level or Tolerance Footnote3 (edible portion) USEPA Screening Values Footnote4 (edible portion)
Total PCB 500 2000** 10
Total DDT 50 5000 300
aldrin * 300**,*** -
dieldrin * 300**,*** 7
endrin * 300**,*** 3000
heptachlor * 300**,*** -
heptachlor epoxide * 300**,*** 10
lindane 50 - 80
chlordane 50 300 80
endosulfan 50 - 20,000
methoxychlor 50 - -
mirex 50 - 2000
toxaphene 50 5000 100
hexachlorobenzene 50 - 70
any other chlorinated hydrocarbon pesticide 50 -
dicofol - - 10,000
oxyfluorfen - - 800
dioxins/dibenzofurans - - 7x10 -4
terbufos - - 1000
ethion - - 5000
disulfoton - - 500
diazinon - - 900
chlorpyrifos - - 30,000
carbophenothion - - 1000
cadmium - - 10,000
selenium - - 50,000
mercury - 1000**(as methyl mercury) 600

*Limit is 5 ng/g wet weight. Singly or in combination with other substances noted by an asterisk.

**Fish and shellfish.

***Singly or in combination for shellfish

TOXIC HOT SPOT REMEDIATION METHODS

Each candidate toxic hot spot shall be evaluated to determine which technique or techniques would best remediate the toxic hot spot. In determining the remedial action(s), each RWQCB shall identify remediation techniques that are technically feasible and reasonably cost-effective. Selection of the alternatives involves choosing the remediation option that is appropriate for the site (i.e., protective of its beneficial uses). This section contains approaches for addressing both sediment and water remediation activities.

Sediment Remediation Methods

The use of remediation technologies and controls is still emerging. Generally, the field has been dominated by tools developed for navigation dredging, and few full scale treatment systems have been implemented. Footnote5 No one option shall be selected in the cleanup plans especially if a discharger is identified as being responsible for the site (in order to comply with Water Code Section 13360).

Tables 2 through 12 list many of the types of remediation that shall be considered by the RWQCBs in developing the regional toxic hot spot cleanup plans for remediation of sediments in enclosed bays, estuaries and the ocean. For each type of remediation technology, the Tables present: (1) the state of the practice, (2) advantages and effectiveness, (3) limitations of the methods, and (4) any identified research needs.

Each RWQCB shall provide an analysis of a range of treatment technologies or alternatives for comparison of the cost effectiveness. The RWQCBs may elect to not consider one or more of the alternatives (below) if the alternative is not feasible for the site.

1. Treatment of the site sediments only.

Site treatment involves the physical or chemical alteration of material. The treatment must reduce or eliminate the toxicity, mobility, or volume of polluted material. Treatment may be either (a) in situ, or (b) ex situ. In situ treatment requires uniform treatment and confirmation of effectiveness; however, in situ methods generally have not been considered effective in marine sediments.

Ex situ treatment requires a treatment area, or a dedicated site to assure effectiveness.

Types of treatment include:

- in situ bioremediation (Table 2),

- soil washing and physical separation (Table 3),

- chemical separation and thermal desorption (Table 4),

- immobilization (Table 5),

- thermal and chemical destruction (Table 6), and

- ex situ bioremediation (Table 7).

The treatment choice shall be pollutant specific. The choice depends upon the chemical characteristics of the pollutants, as well as physical and chemical characteristics of the sediments; for example, clay content, organic carbon content, salinity, and water content. Some treatment options produce by-products which require further handling. If the safety and effectiveness of treatment options are not well known, bench tests and pilot projects shall be performed prior to authorization of the use of such treatment methods.

2. Dredging: Sediment Removal and Disposal or Reuse

Dredging may be combined with containment or off-site disposal (Table 8). Selection of the method depends upon the concentration of pollutants and the amount of resuspension of sediments caused by the dredge at the removal site and at the disposal site. To reduce the transport of polluted sediment to other areas, silt curtains constructed of geotextile fabrics may be utilized to minimize migration of the resuspended sediments beyond the area of removal. Consideration must also be given to temporary loss of benthic organisms at the removal site and at the disposal site.

Table 2: In-Situ Bioremediation

State of Practice (system maturity, known pilot studies, etc.) Applicability Advantages/Effectiveness Limitations Research Needs
(a) None documented for marine sediments; (b) examples from freshwater sediment are limited to special cases on pilot scale, e.g., chemical stimulation of dehalogenation (but no degradation) of PCBs in the Houseatonic River, Connecticut; (c) stimulation of degradation with addition of active microbes in Hudson River, New York. (a) Pollutant is biologically available; (b) concentration of pollutant appropriate for bioactivity, e.g., sufficiently high to serve as substrate or not high enough to be toxic; (c) limited number or classes of pollutants that are biodegradable; less known for complex mixtures; (d) site is reasonably accessible for management and monitoring; (e) rapid solution is not required. Based on experience from soil systems, it offers the potential for (a) complete degradation and elimination of organic pollutants; (b) reduced toxicity of sediment from partial biotransformation; (c) less materials handling, which can result in substantially lower costs; (d) no need for placement sites; (e) favorable public response and acceptability. (a) Not a proven technology for sediments (freshwater or marine); (b) likely to require manipulation and disturbance of sediment; (c) can require containment which limits volume that is treatable; (d) can require long time periods, especially in temperate waters; (e) ineffective for low level pollution; (f) not applicable to areas of high turbulence or sheer; (g) not applicable for high molecular weight polyaromatic hydrocarbons. (a) Fundamental understanding of biodegradation principles in marine environments; (b) bioavailability of sorbed pollutants and the effect of aging; (c) exploration of anaerobic degradation processes for the largely impacted near-shore anoxic sediments; (d) laboratory, pilot, and field demonstration of effectiveness for marine sediments; (e) interaction of physical, chemical, and microbiological processes on biodegradation, e.g., sediment composition, hydrodynamics; (f) analysis of cost- effectiveness; (g) exploration of combining in-situ bioremediation with capping.

Adapted from and reprinted with permission from Contaminated Sediments in Ports and Waterways: Cleanup Strategies and Technologies. Copyright 1997 by the National Academy of Sciences. Courtesy of the National Academy Press, Washington, D.C.

Table 3: Soil Washing and Physical Separation

State of Practice (system maturity, known pilot studies, etc.) Applicability Advantages/Effectiveness Limitations Research Needs
Well developed by mining industry and frequently used for sediments. Where pollutant is predominantly associated with fine-grained material that is a small fraction of the total solids. (a) Mature technology that can reduce volumes of polluted material requiring subsequent treatment; (b) soil washing can be used to recover Confined Disposal Facility space for later reuse. Original sediments must have a significant proportion of sand for the process to be cost effective. None identified.

Adapted from and reprinted with permission from Contaminated Sediments in Ports and Waterways: Cleanup Strategies and Technologies. Copyright 1997 by the National Academy of Sciences. Courtesy of the National Academy Press, Washington, D.C.

Table 4: Chemical Separation and Thermal Desorption

State of Practice (system maturity, known pilot studies, etc.) Applicability Advantages/Effectiveness Limitations Research Needs
(a) Pilot plant studies conducted on metal desorption by acid-leaching solutions and at least one full-scale implementation; (b) pilot and full-scale application of organics separation by liquid solvents and supercritical fluids; (c) organic chemical thermal desorption also has had full-scale demonstration; (d) thermal desorption used at Waukegan Harbor. Suitable for weakly bound organics and metals. Pollutant is removed and concentrated. (a) Batch extraction during separation requires multiple cycles to achieve high removal; (b) fluid-solid separation is difficult for fine-grained materials; (c) a separate reactor is needed to remove the pollutant from the extracting fluid so that the extracting fluid can be reused; (d) thermal desorption requires temperatures that will vaporize water, and sediment particles must be eliminated from gaseous discharge; (e) pollutant removal from the gas phase following thermal desorption is another treatment process that is required. Systems integration for complete pollutant isolation or destruction.

Adapted from and reprinted with permission from Contaminated Sediments in Ports and Waterways: Cleanup Strategies and Technologies. Copyright 1997 by the National Academy of Sciences. Courtesy of the National Academy Press, Washington, D.C.

Table 5: Immobilization

State of Practice (system maturity, known pilot studies, etc.) Applicability Advantages/Effectiveness Limitations Research Needs
Extensive knowledge based on inorganic immobilization within solid wastes and dry soils. Chemical fixation and immobilization of trace metals. (a) Chemical isolation from biologically accessible environment; (b) process is simple and there is a history of use for sludge. (a) Sediment should have moisture content of less than 50 percent, and solidified volumes can be 30 percent greater than starting material; (b) limited applicability to organic pollutants; (c) high organic pollutant levels may interfere with treatment for metals immobilization; (d) need for placement of solidified sediments. (a) Studies of long-term effectiveness for pollutant isolation; (b) develop sediment placement options, especially for beneficial uses.

Adapted from and reprinted with permission from Contaminated Sediments in Ports and Waterways: Cleanup Strategies and Technologies. Copyright 1997 by the National Academy of Sciences. Courtesy of the National Academy Press, Washington, D.C.

Table 6: Thermal and Chemical Destruction

State of Practice (system maturity, known pilot studies, etc.) Applicability Advantages/Effectiveness Limitations Research Needs
Thermal oxidation in flame and thermal reduction in nonflame reactors have been extensively tested and demonstrated. Process destroys organic pollutants in sediment samples at efficiencies of greater than 99.99 percent but at very high costs. Very effective. (a) Very expensive; (b) metals mobilized into the gas phase require gas phase scrubbing; (c) water content of sediment increases energy costs. (a) process control to prevent upsets and effluent gas treatment for metals containment; (b) facility design to control the destruction process.

Adapted from and reprinted with permission from Contaminated Sediments in Ports and Waterways Cleanup Strategies and Technologies. Copyright 1997 by the National Academy of Sciences. Courtesy of the National Academy Press, Washington, D.C.

Table 7: Ex Situ Bioremediation

State of Practice (system maturity, known pilot studies, etc.) Applicability Advantages/Effectiveness Limitations Research Needs
(a) Limited experience; (b) transfer of soil-based technologies to marine sediments is not proved and may not be directly applicable because of the different biogeochemistry of marine sediments; (c) but general trends should translate; (d) examples from freshwater sediment have been carried out at the pilot scale in the assessment and remediation of polluted sediments program, as well as in Europe; (e) PCBs were treated ex situ at a Sheboygan River site. (a) Pollutant is biologically available; (b) concentration of pollutant appropriate for bioactivity (e.g., sufficiently high to serve as substrate, not high enough to be toxic); (c) limited number or classes of pollutants are biodegradable; less known for complex mixtures; (d) site is reasonable accessible for management and monitoring; (e) rapid solution is not required. Based on experience from freshwater systems, it offers the potential for (a) degradation (as opposed to mass transfer) of some organic pollutants; (b) possible reduction of toxicity from biotransformation in those cases in which complete mineralization does not occur; (c) containment of polluted material allowing for an engineered system and enhanced rates, when compared to in situ biotransformations; (d) public acceptability. (a) Far from a proven technology--all work with marine sediments is at the bench-scale; (b) requires handling of polluted sediment; (c) slow compared to chemical treatment; (d) ineffective for low levels of pollution, and does not remove 100 percent of pollutants; (e) not applicable for very complex organics, such as high-molecular-weight compounds; (f) usceptible to matrix effects on bioavailability. (a) Fundamental understanding of biodegradation principles in engineered systems; (b) exploration of aerobic/anaerobic combinations or comparisons; (c) laboratory, pilot, and field demonstrations; (d) analysis of cost effectiveness; (e) exploration of bioremediation as part of more extensive treatment trains.

Adapted from and reprinted with permission from Contaminated Sediments in Ports and Waterways: Cleanup Strategies and Technologies. Copyright 1997 by the National Academy of Sciences. Courtesy of the National Academy Press, Washington, D.C.

Table 8: Confined Disposal Facility

State of Practice (system maturity, known pilot studies, etc.) Applicability Advantages/Effectiveness Limitations Research Needs
(a) The most commonly used placement alternative for polluted sediments; (b) hundreds of sites nationwide for navigation dredging projects; (c) often used for pretreatment prior to final placement or as final sediment placement site for remediation projects. Applicable to a wide variety of sediment types and project conditions. (a) Low cost compared to ex situ treatment; (b) compatible with a variety of dredging techniques, especially direct placement by hydraulic pipeline; (c) proper design results in high retention of suspended sediments and associated pollutants; (d) engineering for basic containment normally involves conventional technology; (e) controls for pollutant pathways usually can be incorporated into site design and management; (f) conventional monitoring approaches can be used; (g) site can be used for beneficial purposes following closure, with proper safeguards. (a) Does not destroy or detoxify pollutants unless combined with treatment; (b) control of some pollutant loss pathways may be expensive. (a) Design approaches, such as covers and liners, needed for low cost pollutant controls; (b) design criteria for treatment of releases or control strategies for high profile contaminates; (c) methods for site management to allow restoration of site capacity and potential use of treated materials.

Adapted from and reprinted with permission from Contaminated Sediments in Ports and Waterways: Cleanup Strategies and Technologies. Copyright 1997 by the National Academy of Sciences. Courtesy of the National Academy Press, Washington, D.C.

Selection of the dredging method shall take into account the physical characteristics of the sediments, the sediment containment capability of the methods employed, the volume and thickness of sediments to be removed, the water depth, access to the site, currents, and waves. Consideration shall also be given to placement site of the material once it is removed.

Typical dredging methods include mechanical or hydraulic dredging. Mechanical dredging often employs clamshell buckets and dislodges sediments by direct force. Sediments can be resuspended by the impact of the bucket, by the removal of the bucket, and by leakage of the bucket. Mechanical dredging generally produces sediments low in water content.

Hydraulic dredging uses centrifugal pumps to remove sediments in the form of a slurry. Although less sediment may be resuspended at the removal site, sediment slurries contain a very high percentage of water at the end of the pipe.

Removal and consolidation often involves a diked structure which retains the dredged material (Tables 9 and 10). Considerations include:

A. construction of the dike or containment structure to assure that pollutants do not migrate,

B. the period of time for consolidation of the sediments,

C. disturbance or burying of benthic organisms,

D. disposal to an off-site location, either upland (landfill), in-bay, or ocean. Considerations once the material has been dredged shall be (1) staging or holding structures or settling ponds, (2) de-watering issues, including treatment and discharge of wastewater, (3) transportation of dredged material, (i.e., pipeline, barge, rail, truck), or (4) regulatory constraints.

Table 9: Contained Aquatic Disposal

State of Practice (system maturity, known pilot studies, etc.) Applicability Advantages/Effectiveness Limitations Research Needs
Limited application. Reviews exist concerning (a) necessary data, equipment, and procedures; (b) engineering considerations; (c) guidelines for cap armoring design; (d) predicting chemical containment effectiveness. (a) Costs and environmental effects of relocation are factors; (b) suitable types and quantities of cap material are available; (c) hydrologic conditions will not compromise the cap; (d) cap can be supported by original bed; (e) appropriate for sites where excavation is problematic or removal efficiency is low; (f) cap material is compatible with existing aquatic environment. (a) Eliminates need to remove polluted sediments; (b) cost effective for sites with large surface areas; (c) effective in containing pollutants by reducing bioaccessibility; (d) promotes in situ chemical or biological degradation; (e) maintains stable geochemical and geohydraulic conditions, minimizing pollutant release to surface water, groundwater, and air. (a) Laboratory and field validation of capping procedures and tools; (b) analysis of data from existing and ongoing field demonstrations to support capping effectiveness; (c) test for chemical release during bed placement and consolidation; (d) tests to evaluate and simulate the effects of cap penetration by deep burrowing organisms; (e) simulate and evaluate consequences of mixing; (f) potential loss of pollutants to the water column may require controls during placement. (a) Design criteria for treatment of releases or control strategies for high-profile pollutants; (b) improved methods for evaluation of potential pollutant release pathways; (c) develop reliable cost estimates.

Adapted from and reprinted with permission from Contaminated Sediments in Ports and Waterways: Cleanup Strategies and Technologies. Copyright 1997 by the National Academy of Sciences. Courtesy of the National Academy Press, Washington, D.C.

Table 10: Landfills

State of Practice (system maturity, known pilot studies, etc.) Applicability Advantages/Effectiveness Limitations Research Needs
Used for several dredged material and Superfund projects involving polluted sediments. (a) Small volumes; (b) where no other alternatives or sites are available. (a) Does not require acquisition of permanent placement site; (b) may be most cost effective for small volumes; (c) effectiveness is inherent in the site license. (a) Lack of landfill capacity in most regions of the country; (b) requires handling and transport to the landfill; (c) restriction on free liquids requires dewatering as a pretreatment step. Improved methods for rehandling, dewatering, and transporting dredged sediments.

Adapted from and reprinted with permission from Contaminated Sediments in Ports and Waterways: Cleanup Strategies and Technologies. Copyright 1997 by the National Academy of Sciences. Courtesy of the National Academy Press, Washington, D.C.

3. Containment of Polluted Sediments

Containment can prevent human or ecological exposure, or prevent migration of pollutants. Containment can be either in-place capping, or removal and consolidation at a disposal structure (Tables 9 and 11). Containment options such as capping clearly reduce the short-term exposure, but require long-term monitoring to track their effectiveness.

The considerations for stabilization of sites using sub-aqueous capping to contain toxic waste at a site includes:

A. Capping provides adequate coverage of polluted sediments and capping materials can be easily placed.

B. The integrity of the cap should be assured to prevent burrowing organisms from mixing of polluted sediments (bioturbation).

C. The ability of the polluted sediment to support the cap, i.e., causing settlement or loading.

D. The bottom topography causing sloping or slumping of the capped material during seismic events.

E. Cap erosion or disruption by currents, waves, bioturbation, propeller wash, or ship hulls.

F. Future use of capped area, i.e., use as shipping channel.

4. No Remediation

This alternative consists of two elements: (a) institutional or interim controls and (b) the natural remediation or no-action alternative. The first element, institutional controls, could include, but is not limited to, posting of warning signs, or monitoring of water, sediments, or organisms. This element would be protective of human health by providing warning signs for fishing, etc., but not protective of aquatic life.

Table 11: In-Place Capping

State of Practice (system maturity, known pilot studies, etc.) Applicability Advantages/Effectiveness Limitations Research Needs
Less than 10 major in situ capping projects in North America have been completed (more than 20 worldwide). Reviews exist concerning (a) necessary data, equipment, and procedures; (b) engineering considerations; (c) guidelines for design of cap armor; and (d) predicting effectiveness of chemical containment. (a) Pollutant sources have been substantially abated; (b) natural recovery is too slow; (c) costs and environmental effectiveness of relocation are too high; (d) suitable types and quantities of cap material are available; (e) hydrologic conditions will not compromise the cap; (f) cap can be supported by original bed; (g) appropriate for sites where excavation is problematic or removal efficiency is low. (a) Eliminates need to remove polluted sediments; (b) effective in containing pollutants by reducing bioaccessibility; (c) promotes in situ chemical or biological degradation; (d) maintains stable geochemical and geohydraulic conditions, minimizing pollutant release to surface water, groundwater, and air; (e) relatively easy to implement; (f) eliminates bioturbation and resuspension; (g) reduces pollutant release to water column; (h) easily replaced or repaired; (i) in shallow water, creates wetlands, dry lands, or reduces water column depth. (a) Cap incompatible with bottom material can alter benthic community; (b) subject to erosion by strong currents and wave action; (c) subject to penetration/destruction by deep burrowing organisms; (d) destroys/changes benthic communities/ecological niches; (e) requires ongoing monitoring for cap integrity; (f) dilutes pollutants in original bed if subsequent removal/remediation is required. (a) Analysis of data from existing and ongoing field demonstrations to support capping effectiveness; (b) controls for chemical release during bed placement and consolidation; (c) test to simulate and evaluate consequences of episodic mixing, such as anchor penetration, propeller wash, and/or mechanical penetration.

Adapted from and reprinted with permission from Contaminated Sediments in Ports and Waterways: Cleanup Strategies and Technologies. Copyright 1997 by the National Academy of Sciences. Courtesy of the National Academy Press, Washington, D.C.The second element is the natural remediation or no-action alternative. If by no action, the toxic hot spot is to be left in place, because to move it, or to disturb it in any way would be detrimental, then "no action" shall be considered as the last alternative. The natural remediation/no-action alternative shall be considered only after all other alternatives have been studied.

If the natural remediation/no-action alternative is to be implemented, the RWQCB shall consider all the factors specified in Table 12 plus determine the following: (a) point source discharges have been controlled, (b) the costs and environmental effects of moving and treating polluted sediment are too great, (c) hydrologic conditions will not disturb the site, (d) the sediment will not be remobilized by human or natural activities, such as by shipping activity or bioturbation, (e) notices to abandon the site have been issued to appropriate federal, state, and local agencies and to the public, (f) the exact location of the site and a list of chemicals causing the toxic hot spot and their quantities are noted on deeds, maps, and navigational charts, and (g) a monitoring program is established to measure changes in discharge rates from the site.

If a natural remediation alternative is considered, RWQCBs shall provide an assessment of the geographic extent of the pollution, the depth of the pollution in the sediment, compelling evidence that no treatment technologies shall be applied and that only the natural remediation alternative is feasible at the site, and a cleanup cost comparison of all other treatment technologies versus the no-remediation alternative.

If a natural remediation alternative is considered, the following information shall be provided in the Regional cleanup plan:

A. Sources of pollution which caused the toxic hot spot to exist.

B. A monitoring program description, specifying the duration of the monitoring, and all organizations which will carry it out.

C. Monitoring program which will show whether rates of pollutant release and the area of influence of the pollutants are not accelerating.

D. Detailed assessment containing proof that all of the following statements are true:

(1) Pollutant discharge has been controlled.

(2) Burial or dilution processes are rapid.

(3) Sediment will not be remobilized by human or natural activities.

(4) Environmental effects of cleanup are equal to or more damaging than leaving the sediment in place.

(5) Unpolluted sediments from the drainage basin will integrate with polluted sediments through a combination of dispersion, mixing, burial, and/or biological degradation.

(6) Polluted sediments at the site will not spread.

(7) The site will be noted on appropriate maps, charts, and deeds to document the exact location of the site.

For no-remediation alternatives, a map of the area shall be required to be provided by potential discharger(s) to the U.S. Army Corps of Engineers, U.S. Coast Guard, National Oceanic and Atmospheric Administration, Coastal Commission, State Lands Commission, and harbor authorities to be included on official navigational charts and other maps to document the exact location of the site and the depth of the site and the pollutants encountered.

Table 12: Natural Recovery

State of Practice (system maturity, known pilot studies, etc.) Applicability Advantages/Effectiveness Limitations Research Needs
Selected for James River, New York Kepone pollution and considered at Port of Tacoma, Washington site. (a) Bed is stable or depositional; (b) chemical release rates are low; (c) interim controls can maintain safety to health and environment; (d) ollution level at active surface is low, but areal extent is large; (e) most of the pollution is below the bioturbed zone; (f) pollutants are underlain by low permeability strata; (g) site is not subject to dredging or other disturbance; (h) source of pollution has been abated. (a) There may be less environmental risk to await natural capping than to attempt sediment removal; (b) removal may cause physical harm to bottom communities as well as suspend and disperse pollutants; (c) cleanup cost may be prohibitive because of large area and low level of pollution; (d) low cost. (a) Effectiveness of in-bed processes that govern chemical containment and/or destruction is poorly known; (b) bed remains subject to resuspension by storms or anthropogenic processes; (c) should only rarely be used in beds of flowing streams; (d) not appropriate if dredging is required or bulk quantities of chemicals, such as non-aqueous liquids or solids, are present. (a) Develop scientific principles to describe the process of natural recovery; (b) based on a literature survey, document the success, failure, effectiveness, etc., of sites that have undergone natural recovery either by design or default; (c) develop accepted measuring protocols to determine in situ chemical flux from bed sediment to the overlying water column; (d) develop protocols for assessing the relative contribution of the five or more mechanisms for chemical release or movement from bed sediments.

Adapted from and reprinted with permission from Contaminated Sediments in Ports and Waterways: Cleanup Strategies and Technologies. Copyright 1997 by the National Academy of Sciences. Courtesy of the National Academy Press, Washington, D.C. Remediation Methods for Water-related Toxic Hot Spots

The three basic approaches which may be practiced independently or concurrently are pollution prevention, pretreatment and recycle and reuse. The RWQCBs shall develop prevention activities tailored to local conditions and the tools available. The RWQCBs shall also provide enough flexibility to dischargers so they can select the most cost-effective approaches for addressing wastewater-related problems. If the RWQCBs have more recent or site-specific information on treatment technology, the RWQCB may use an alternative approach. If the RWQCB cannot determine which prevention tools will be most effective, the selection of methods to address water-related toxic hot spots should be made during the implementation of watershed management approaches that contrast alternate ways to solve the identified problems.

A large number of technically feasible wastewater treatment methods are available. In developing the cleanup plans the RWQCBs shall base their assessments of possible treatment technologies on the effectiveness of removing the pollutant(s) of concern. No one option shall be selected in the cleanup plans especially if discharger(s) are identified as being responsible for the toxic hot spot (in order to comply with Water Code Section 13360). Methods for addressing stormwater and nonpoint sources are emerging and RWQCBs should use their best judgment in suggesting approaches (and their costs).

REMEDIATION COSTS

Sediment Cleanup Costs

Total costs for various remedial technologies is dependent upon many factors, some of the most important being pollutant concentration, cleanup level, physical characteristics of the sediment, and the volume of material to be remediated. In addition, overall costs of remediation should also include monitoring to evaluate the effectiveness of cleanup. Due to the large number of variables associated with remedial actions and availability of disposal sites, the costs for any cleanup will necessarily be project specific.

Tables 13 and 14 provide a qualitative assessment of the various categories of technology. RWQCBs shall use either the estimates in Table 13 and Table 14 or use project-specific estimates of cleanup costs. Obtaining new estimates will allow a more realistic comparison of the cost-effectiveness and benefits of the selected alternatives.

Wastewater Treatment System, Stormwater, or Nonpoint Source Costs

The costs for implementing the waste water treatment technologies and best management practices are discharge- and site-specific. In developing estimates the RWQCBs shall use the EPA Treatability Manual, applicable National Research Council reports, site-specific estimates, or delay the development of cost estimates if the toxic hot spot will be addressed as part of a watershed management effort. If cost estimates are delayed the RWQCBs shall develop cost estimates for developing and coordinating the watershed planning effort.

BENEFITS OF REMEDIATION

In developing the regional toxic hot spot cleanup plans the RWQCBs will list the benefits that will be derived by remediating candidate toxic hot spots. It is acknowledged that the benefits to be developed by the RWQCBs are qualitative estimates. The list of possible benefits of remediation are presented in Table 15.

Table 13: Qualitative Comparison of the State of the Art in Remediation Technologies


Feature technology


State of Design Guidance


Number of Times Used


Scale of Application


Cost (per cubic yard)


Limitations

Natural recovery Nonexistent 2 Full scale. Low. Source control Sedimentation Storms.
In place containment Developing rapidly <10 Full scale. <$20. Limited technical guidance. Legal/regulation uncertainty.
In place treatment Nonexistent ~2 Pilot scale. Unknown. Technical problems. Few proponents. Need to treat entire volume.
Excavation and containment. Substantial and well developed Several hundred Full scale. $20 to $100. Site availability

Public assistance.

Excavation and treatment Limited and extrapolated from soil <10 Full scale. $50 to $1,000. High cost. Inefficient for low concentration. Residue toxic. Need for treatment train.

Adapted from and reprinted with permission from Contaminated Sediments in Ports and Waterways: Cleanup Strategies and Technologies. Copyright 1997 by the National Academy of Sciences. Courtesy of the National Academy Press, Washington, D.C.

Table 14: Comparative Analysis of Sediment Technology Categories

Approach Feasibility Effective Practicality Cost

INTERIM CONTROL

Administrative

Technological



LONG-TERM CONTROL

In Situ

Natural recovery

Capping

Treatment



Sediment Removal and Transport



Ex Situ Treatment

Physical

Chemical

Thermal

Biological



Ex Situ Containment



0

1





0

2

1



2




1

1

4

0



2



4

3





4

3

1



4




4

2

4

1



4



2

1





1

3

2



3




4

4

3

4



2



4

3





4

3

2



2




1

1

0

1



2

SCORING

0


1

2

3

4

Feasibility

<90%


90%

99%

99.9%

99.99%

Effective

Concept


Bench

Pilot

Field

Commercial

Practicality

Not acceptable, very uncertain




Acceptable, certain

Cost

$1,000/yd


$100/yd

$10/yd

$1/yd

<$1/yd



Adapted from and reprinted with permission from Contaminated Sediments in Ports and Waterways Cleanup Strategies and Technologies. Copyright 1997 by the National Academy of Sciences. Courtesy of the National Academy Press, Washington, D.C.

Table 15. Beneficial Effects of Remediation

Beneficial
effect
Values quantifying these beneficial effects Beneficial use affected
Lower toxicity in planktonic and benthic organisms Greater survival of organisms in toxicity tests. MAR, EST
Undegraded benthic community Species diversity and abundance characteristic of undegraded conditions. MAR, EST
Lower concentrations of pollutants in water Water column chemical concentration that will not contribute to possible human health impacts. MIGR, SPWN, EST, MAR, REC 1, REC 2
Lower concentrations of pollutants in fish and shellfish tissue Lower tissue concentrations of chemicals that could contribute to possible human health and ecological impacts. MAR, EST, REC 1, COMM
Area can be used for sport and commercial fishing. Anglers catch more fish. Impact on catches and net revenues of fishing operations increase. REC 1, COMM
Area can be used for shellfish harvesting or aquaculture Jobs and production generated by these activities increase. Net revenues from these activities are enhanced. SHELL, AQUA
Improved conditions for seabirds and other predators Increase in populations. Value to public of more abundant wildlife. WILD, MIGR, RARE
More abundant fish populations Increase in populations. Value to public of more abundant wildlife. MAR, EST
Commercial catches increase Impact on catches and net revenues of fishing operations. COMM
Recreational catches increase, more opportunities for angling Increased catches and recreational visitor-days. REC 1
Improved ecosystem conditions Species diversity and abundance characteristic of undegraded conditions. EST, MAR
Improved aesthetics Value to public of improved aesthetics. In some cases, estimates of the value to the public of improved conditions may be available from surveys. REC 2
More abundant wildlife, more opportunities for wildlife viewing Impact on wildlife populations. Impact on recreational visitor-days. MAR, WILD, RARE, REC 2

PREVENTION OF TOXIC HOT SPOTS

In the process of developing strategies to remediate toxic hot spots related to both sediment and water, the RWQCBs shall focus on approaches that rely on existing State and Federal programs to address identified toxic hot spots. In addressing prevention activities for point and nonpoint sources of pollution, the RWQCBs shall:

1. Consider use of any established prevention tools such as (a) voluntary programs, (b) interactive cooperative programs, and (c) regulatory programs, individually or in any combination that will result in an effective toxic hot spot prevention strategy. The RWQCBs shall consider site-specific and pollutant-specific strategies to address the toxic hot spot including, but not limited to: pollution prevention audits, studies to specifically identify sources of pollutants, total maximum daily load development, watershed management approaches, pretreatment, recycle and reuse, revised effluent limitations, prohibitions, implementation of best management practices, etc.

2. Promote a watershed management protection approach focused on hydrologically defined areas (watersheds) rather than areas defined by political boundaries (counties, districts, municipalities), that take into account all waters, surface, ground, inland, and coastal and address point and nonpoint sources of pollution that may have influence or has been identified to have influenced the identified toxic hot spots. Link the cleanup plan to implementation of the Watershed Management Initiative and the SWRCB Strategic Plan.

3. Encourage the participation and input of, interdisciplinary groups of interested parties (including all potential dischargers) that are able to cross over geographical and political boundaries to develop effective solutions for preventing toxic hot spots.

4. Use prevention strategies that provide enough flexibility to be used as watershed protection plans where there are none established or have the ability to join with a watershed protection plan that is already being implemented to address the toxic hot spot. Solutions developed shall also be developed for, and applied at sites where it will do the most prevention and where it will be the most cost-effective at mitigating and preventing toxic hot spots at a watershed level.

Pesticide residues should not be considered under the Bay Protection and Toxic Cleanup Program if they are detected in the water column in a pattern of infrequent pulses moving by the sampling location. Such detections will be addressed using cooperative approaches such as the Management Agency Agreement between the SWRCB and the Department of Pesticide Regulation, the NPS Management Plan, and existing authorities including the Porter-Cologne Water Quality Control Act and Clean Water Act.

SITE-SPECIFIC VARIANCES

A site-specific variance to this Policy may be granted if an alternate approach for developing a cleanup plan for one or more sites within the jurisdiction of a RWQCB is needed. In all cases, when a RWQCB takes an alternate approach, the RWQCB shall provide the following information to the SWRCB prior to incorporation into the regional toxic hot spot cleanup plan:

1. A description of the provision not followed.

2. A description of the new approach used. The proposed alternative program, method, or process shall be clearly identified.

3. Any specific circumstances on which the RWQCB relied to justify the finding necessary for the variance.

4. Clear evidence that the alternative approach will better protect beneficial uses.

No variance from this Policy shall be effective unless approved by the SWRCB Executive Director.

ISSUES TO BE CONSIDERED IN THE DEVELOPMENT OF THE CONSOLIDATED TOXIC HOT SPOT CLEANUP PLAN

The SWRCB is required to develop a consolidated toxic hot spot cleanup plan. The regional toxic hot spot cleanup plans that are developed with this Policy will not become effective until the consolidated plan is completed. In developing the consolidated plan the SWRCB will consider several issues including, but not limited to:

1. Approaches for consolidating and compiling regional toxic hot spot cleanup plans.

2. Removing locations from and reevaluating the list of known toxic hot spots.

3. Guidance to the RWQCBs on considerations when reevaluating waste discharger requirements in compliance with Water Code Section 13395.

4. Findings concerning implementation of the plan and the need for establishment of a toxic hot spot cleanup program to fund remediation activities (consistent with Water Code Section 13394(i)).

TEMPLATE FOR PROPOSED REGIONAL TOXIC HOT SPOT CLEANUP PLANS

The regional toxic hot spot cleanup plan shall be formatted as presented below.

REGIONAL TOXIC HOT SPOT CLEANUP PLAN

REGIONAL WATER QUALITY CONTROL BOARD REGION

Part I

I. Introduction

Region Description

Legislative Authority

Limitations

II. Toxic Hot Spot Definition

Codified Definition of A Toxic Hot Spot

Specific Definition of A Toxic Hot Spot

III. Monitoring Approach

IV. Criteria For Ranking Toxic Hot Spots

Human Health

Aquatic Life

Water Quality Objectives

Other Factors

V. Future Needs

Part II

VI. Candidate Toxic Hot Spot List

Water body name Segment Name Site Identification Reason for Listing Pollutants present at the site. Report reference
















































Reference list

V. Ranking Matrix

Water body Name Site Identification Human Health Impacts Aquatic Life Impacts Water Quality Objectives Areal Extent Remediation Potential Overall Ranking
























































Part III

V. High Priority Candidate Toxic Hot Spot Characterization

For each high priority Candidate Toxic Hot Spot, the following information shall be presented:

A. An assessment of the areal extent of the THS.

B. An assessment of the most likely sources of pollutants (potential discharger).

C. A summary of actions that have been initiated by the Regional Boards to reduce the accumulation of pollutants at existing THSs and to prevent the creation of new THSs.

D. Preliminary Assessment of Actions required to remedy or restore a THS including recommendations for remedial actions.

E. An estimate of the total cost and benefits of implementing the cleanup plan.

F. An estimate of recoverable costs from potential dischargers.

G. A two-year expenditure schedule identifying funds to implement the plans that are not recoverable from potential dischargers.

Footnote1

1 Water quality objectives to be used are found in Regional Water Quality Control Board Basin Plans or the California Ocean Plan (depending on which plan applies to the water body being addressed). Where a Basin Plan contains a more stringent value than the statewide plan, the regional water quality objective will be used.

Footnote2

National Academy of Sciences. 1973. Water Quality Criteria, 1972 (Blue Book). The recommendation applies to any sample consisting of a homogeneity of 25 or more fish of any species that is consumed by fish-eating birds and mammals, within the same size range as the fish consumed by any bird or mammal. No NAS recommended guidelines exist for marine shellfish.

Footnote3

U.S. Food and Drug Administration. 1984. Shellfish Sanitation Interpretation: Action Levels for Chemical and Poisonous Substances. A tolerance, rather than an action level, has been established for PCB.

Footnote4

U.S. Environmental Protection Agency. 1993. Guidance for assessing chemical contaminant data for use in fish advisories. Volume 1. EPA 823-R-93-002. Office of Water. Washington, D.C.

Footnote5

National Research Council. 1997. Contaminated sediments in ports and waterways: Cleanup strategies and technologies. Committee on Contaminated Marine Sediments, Marine Board, Commission on Engineering and Technical Systems, National Research Council. National Academy Press, Washington, D.C. 295 pp.