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{"sheet":"Cyanotoxin-Calc","index":0,"n_rows":41,"n_cols":15,"rows_kept":41,"cut":false,"hidden":false,"merged":[]}
[null,"Author:  Guy Schott, P.E., guy.schott@waterboards.ca.gov, 707-576-2732",null,null,null,"V.2: Last updated August 21, 2015"]
[]
[null,"Microcystin-LR (MC-LR) Reduction via Free Chlorine Residual",null,null,null,null,null,null,null,"Cylindrospermopsin (CYN) Reduction via Free Chlorine Residual"]
[]
[null,"Model 1","CT Calculation for Microcystin-LR (MC-LR)",null,null,null,null,null,null,"Model 1","CT Calculation for Cylindrospermopsin (CYN) "]
[null,"Enter water quality parameters:",null,null,null,null,null,null,null,"Enter water quality parameters:"]
[null,"pH",8,"unit","Results:",null,null,null,null,"pH",8.5,"unit","Results:"]
[null,"Temperature",15,"oC","CT",{"$f":"F9*60/(1000*2*35.45)","v":0.2016083432830077},"mol ∙ sec",null,null,"Temperature",10,"oC","CT",{"$f":"N9*60/(1000*2*35.45)","v":6.1356336703136831E-2},"mol ∙ sec"]
[null,"Initial MC-LR",100,"ug/L","CT",{"$f":"-LN(_Mc/_Mco)/(((2.07*10^7)*(10^(-_pHmicro))^2+(3.152*_Tempmicro+53.74)*10^-_pHmicro+(0.181*_Tempmicro+3.2)*10^-7.5)/(10^-7.5+10^-_pHmicro))*(35.45*2*1000/60)","v":238.23385897942077},"mg/L ∙ min",null,null,"Initial CYN",500,"ug/L","CT",{"$f":"LN(K10/K9)*1/(-EXP((0.02318747*K7^5-0.73000317*K7^4+8.86614878*K7^3-52.12019339*K7^2+149.8450036*K7-152.54823628)-32700/(8.3145*(273.15+K8))))/(1/1000/70.096)/60","v":72.502737870873347},"mg/L ∙ min"]
[null,"Final MC-LR",0.3,"ug/L","Log (%) Reduction",{"$f":"TEXT(LOG(C9/C10),\"#0.0\") & \", (\" & TEXT((1-C10/C9)*100,\"#.0\") & \"%)\"","v":"2.5, (99.7%)"},"unit",null,null,"Final CYN",0.7,"ug/L","Log (%) Reduction",{"$f":"TEXT(LOG(K9/K10),\"#0.0\") & \", (\" & TEXT((1-K10/K9)*100,\"#.0\") & \"%)\"","v":"2.9, (99.9%)"},"unit"]
[]
[null,"Model 2","Initial Microcystin-LR (MC-LR) Calculation",null,null,null,null,null,null,"Model 2","Initial Cylindrospermospsin (CYN) Calculation"]
[null,"Enter water quality parameters:",null,null,null,null,null,null,null,"Enter water quality parameters:"]
[null,"pH",8,"unit","Results:",null,null,null,null,"pH",8.6999999999999993,"unit","Results:"]
[null,"Temperature",20,"oC","CT",{"$f":"_CTop*60/(1000*2*35.45)","v":0.10155148095909731},"mol ∙ sec",null,null,"Temperature",20,"oC","CT",{"$f":"K16*60/(1000*2*35.45)","v":2.9619181946403384E-2},"mol ∙ sec"]
[null,"Operating CT",120,"mg/L ∙ min","Initial MC-LR",{"$f":"EXP(((2.07*10^7)*(10^(-_pHmicro2))^2+(3.152*_Tempmicro2+53.74)*10^-_pHmicro2+(0.181*_Tempmicro2+3.2)*10^-7.5)/(10^-7.5+10^-_pHmicro2)*F15)*_MCf2","v":8.8151238484812069},"ug/L",null,null,"Operating CT",35,"mg/L ∙ min","Initial CYN",{"$f":"IF((EXP((-EXP((0.02318747*K14^5-0.73000317*K14^4+8.86614878*K14^3-52.12019339*K14^2+149.8450036*K14-152.54823628)-32700/(8.3145*(273.15+K15))))*K16*60*1/1000/70.096)/K17)^-1>10000,\">10,000\",(EXP((-EXP((0.02318747*K14^5-0.73000317*K14^4+8.86614878*K14^3-52.12019339*K14^2+149.8450036*K14-152.54823628)-32700/(8.3145*(273.15+K15))))*K16*60*1/1000/70.096)/K17)^-1)","v":15.415842316573798},"ug/L"]
[null,"Final MC-LR",0.3,"ug/L","Log (%) Reduction",{"$f":"TEXT(LOG(F16/C17),\"#0.0\") & \", (\" & TEXT((1-C17/F16)*100,\"#.0\") & \"%)\"","v":"1.5, (96.6%)"},"unit",null,null,"Final CYN",0.7,"ug/L","Log (%) Reduction",{"$f":"IF((EXP((-EXP((0.02318747*K14^5-0.73000317*K14^4+8.86614878*K14^3-52.12019339*K14^2+149.8450036*K14-152.54823628)-32700/(8.3145*(273.15+K15))))*K16*60*1/1000/70.096)/K17)^-1>10000,\">4.0 (100%)\",TEXT(LOG(N16/K17),\"#0.0\") & \", (\" & TEXT((1-K17/N16)*100,\"#.0\") & \"%)\")","v":"1.3, (95.5%)"},"unit"]
[]
[null,"Model 3","Initial Microcystin-LR (MC-LR) Calculation",null,null,null,null,null,null,"Model 3","Initial Cylindrospermopsin (CYN) Calculation"]
[null,"Enter water quality parameters:",null,null,null,null,null,null,null,"Enter water quality parameters:"]
[null,"pH",7,"unit","Results:",null,null,null,null,"pH",8.8000000000000007,"unit","Results:"]
[null,"Temperature",10,"oC","CT",{"$f":"F23*60/(1000*2*35.45)","v":8.4626234132581094E-2},"mol ∙ sec",null,null,"Temperature",15,"oC","CT",{"$f":"N23*60/(1000*2*35.45)","v":5.9238363892806768E-2},"mol ∙ sec"]
[null,"Chlorine Residual",2,"mg/L","Operating CT",{"$f":"C23*C24*C25","v":100},"mg/L ∙ min",null,null,"Chlorine Residual",1,"mg/L","Operating CT",{"$f":"K23*K24*K25","v":70},"mg/L ∙ min"]
[null,"HRT",50,"minutes","Initial MC-LR",{"$f":"EXP(((2.07*10^7)*(10^(-_pHmicro3))^2+(3.152*_Tempmicro3+53.74)*10^-_pHmicro3+(0.181*_Tempmicro3+3.2)*10^-7.5)/(10^-7.5+10^-_pHmicro3)*F22)*_Mcf3","v":303.90113238510338},"ug/L",null,null,"HRT",140,"minutes","Initial CYN",{"$f":"IF((EXP((-EXP((0.02318747*K21^5-0.73000317*K21^4+8.86614878*K21^3-52.12019339*K21^2+149.8450036*K21-152.54823628)-32700/(8.3145*(273.15+K22))))*N23*60*1/1000/70.096)/K26)^-1>10000,\">10,000\",(EXP((-EXP((0.02318747*K21^5-0.73000317*K21^4+8.86614878*K21^3-52.12019339*K21^2+149.8450036*K21-152.54823628)-32700/(8.3145*(273.15+K22))))*N23*60*1/1000/70.096)/K26)^-1)","v":33.176967298238125},"ug/L"]
[null,"Baffling Factor",1,"t10/T","Final MC-LR",{"$f":"C26","v":1},"ug/L",null,null,"Baffling Factor",0.5,"t10/T","Final CYN",{"$f":"K26","v":0.7},"ug/L"]
[null,"Final MC-LR",1,"ug/L","Log (%) Reduction",{"$f":"TEXT(LOG(F24/C26),\"#0.0\") & \", (\" & TEXT((1-C26/F24)*100,\"#.0\") & \"%)\"","v":"2.5, (99.7%)"},"unit",null,null,"Final CYN",0.7,"ug/L","Log (%) Reduction",{"$f":"IF((EXP((-EXP((0.02318747*K21^5-0.73000317*K21^4+8.86614878*K21^3-52.12019339*K21^2+149.8450036*K21-152.54823628)-32700/(8.3145*(273.15+K22))))*N23*60*1/1000/70.096)/K26)^-1>10000,\">4.0 (100%)\",TEXT(LOG(N24/K26),\"#.0\") & \", (\" & TEXT((1-K26/N24)*100,\"#.0\") & \"%)\")","v":"1.7, (97.9%)"},"unit"]
[]
[]
[null,"Directions:",null,null,null,null,null,null,null,"Directions:"]
[null,"Model 1:  Calculates the CT value based on user inputs ",null,null,null,null,null,null,null,"Model 1:  Calculates the CT value based on user inputs "]
[null,"of water pH, temperature, initial and final microcystin-LR.",null,null,null,null,null,null,null,"of water pH, temperature, initial and final Cylindrospermopsin (CYN)."]
[null,"The user final MC-LR may be inputted down to 0.1 ug/L.",null,null,null,null,null,null,null,"The user final CYN may be inputted down to 0.1 ug/L."]
[]
[null,"Model 2:  Calculates the initial MC-LR that can be treated based on user",null,null,null,null,null,null,null,"Model 2:  Calculates the initial MC-LR that can be treated based on user"]
[null,"inputs of water pH, temperature, operating CT and final microcystin-LR.",null,null,null,null,null,null,null,"inputs of water pH, temperature, operating CT and final microcystin-LR."]
[null,"The user final MC-LR may be inputted down to 0.1 ug/L.",null,null,null,null,null,null,null,"The user final CYN may be inputted down to 0.1 ug/L."]
[]
[null,"Model 3:  Calculates the initial MC-LR that can be treated based on user",null,null,null,null,null,null,null,"Model 3:  Calculates the initial CYN that can be treated based on user"]
[null,"inputs of water pH, temperature, chlorine residual, HRT,",null,null,null,null,null,null,null,"inputs of water pH, temperature, chlorine residual, HRT,"]
[null,"clearwell baffling factor and final microcystin-LR.",null,null,null,null,null,null,null,"clearwell baffling factor and final Cylindrospermopsin."]
[null,"The user final MC-LR may be inputted down to 0.1 ug/L.",null,null,null,null,null,null,null,"The user final CYN may be inputted down to 0.1 ug/L."]

{"sheet":"CT Tables","index":1,"n_rows":59,"n_cols":16,"rows_kept":59,"cut":false,"hidden":false,"merged":[]}
[null,"Author:  Guy Schott, P.E., guy.schott@waterboards.ca.gov, 707-576-2732"]
[]
[null,null,"CT Table for Microcystin-LR based on Free Chlorine Residual"]
[]
[null,null,null,"Temperature: 10 oC",null,null,null,null,null,null,"Temperature: 20 oC"]
[null,null,null,"Log Reduction of Microcystin-LR",null,null,null,null,null," ","Log Reduction of Microcystin-LR"]
[null,null,"pH",0.5,1,1.5,2,2.5,3,"pH",0.5,1,1.5,2,2.5,3]
[null,null,6,{"$f":"$D$7*E8","v":13.225},26.45,{"$f":"E8*$F$7","v":39.674999999999997},{"$f":"$G$7*E8","v":52.9},{"$f":"$H$7*E8","v":66.125},{"$f":"$I$7*E8","v":79.349999999999994},6,{"$f":"$D$7*L8","v":10.195},20.39,{"$f":"L8*$F$7","v":30.585000000000001},{"$f":"$G$7*L8","v":40.78},{"$f":"$H$7*L8","v":50.975000000000001},{"$f":"$I$7*L8","v":61.17}]
[null,null,6.5,16.215,32.43,48.644999999999996,64.86,81.075000000000003,97.289999999999992,6.5,12.07,24.14,36.21,48.28,60.35,72.42]
[null,null,7,20.14,40.28,60.42,80.56,100.7,120.84,7,14.8,29.6,44.400000000000006,59.2,74,88.800000000000011]
[null,null,7.5,29.925000000000001,59.85,89.775000000000006,119.7,149.625,179.55,7.5,21.9,43.8,65.699999999999989,87.6,109.5,131.39999999999998]
[null,null,8,55.895000000000003,111.79,167.685,223.58,279.47500000000002,335.37,8,40.869999999999997,81.739999999999995,122.60999999999999,163.47999999999999,204.35,245.21999999999997]
[null,null,8.5,110.505,221.01,331.51499999999999,442.02,552.52499999999998,663.03,8.5,80.87,161.74,242.61,323.48,404.35,485.22]
[null,null,9,182.10499999999999,364.21,546.31499999999994,728.42,910.52499999999998,1092.6299999999999,9,133.49,266.98,400.47,533.96,667.45,800.94]
[null,null,null,"Temperature: 15 oC",null,null,null,null,null,null,"Temperature: 25 oC"]
[null,null,null,"Log Reduction of Microcystin-LR",null,null,null,null,null," ","Log Reduction of Microcystin-LR"]
[null,null,"pH",0.5,1,1.5,2,2.5,3,"pH",0.5,1,1.5,2,2.5,3]
[null,null,6,{"$f":"$D$7*E18","v":11.515000000000001},23.03,{"$f":"E18*$F$7","v":34.545000000000002},{"$f":"$G$7*E18","v":46.06},{"$f":"$H$7*E18","v":57.575000000000003},{"$f":"$I$7*E18","v":69.09},6,{"$f":"$D$7*L18","v":9.1449999999999996},18.29,{"$f":"L18*$F$7","v":27.434999999999999},{"$f":"$G$7*L18","v":36.58},{"$f":"$H$7*L18","v":45.724999999999994},{"$f":"$I$7*L18","v":54.87}]
[null,null,6.5,13.835000000000001,27.67,41.505000000000003,55.34,69.175000000000011,83.01,6.5,10.7,21.4,32.099999999999994,42.8,53.5,64.199999999999989]
[null,null,7,17.059999999999999,34.119999999999997,51.179999999999993,68.239999999999995,85.3,102.35999999999999,7,13.065,26.13,39.195,52.26,65.325000000000003,78.39]
[null,null,7.5,25.29,50.58,75.87,101.16,126.44999999999999,151.74,7.5,19.309999999999999,38.619999999999997,57.929999999999993,77.239999999999995,96.55,115.85999999999999]
[null,null,8,47.215000000000003,94.43,141.64500000000001,188.86,236.07500000000002,283.29000000000002,8,36.024999999999999,72.05,108.07499999999999,144.1,180.125,216.14999999999998]
[null,null,8.5,93.394999999999996,186.79,280.185,373.58,466.97499999999997,560.37,8.5,71.31,142.62,213.93,285.24,356.55,427.86]
[null,null,9,154.05500000000001,308.11,462.16500000000002,616.22,770.27500000000009,924.33,9,117.77,235.54,353.31,471.08,588.85,706.62]
[null,null,"CT units:","mg/L*min",null,"0.5 Log = 68.4%; 1.0 Log = 90.0%; 1.5 Log = 96.8%; 2 Log = 99.0%; 2.5 Log = 99.7%; 3 Log = 99.9%"]
[]
[null,null,"CT Table for Cylindrospermopsin (CYN) based on Free Chlorine Residual"]
[]
[null,null,null,"Temperature: 10 oC",null,null,null,null,null,null,"Temperature: 20 oC"]
[null,null," ","Log Reduction of Cylindrospermospsin",null,null,null,null,null," ","Log Reduction of Cylindrospermospsin"]
[null,null,"pH",0.5,1,1.5,2,2.5,3,"pH",0.5,1,1.5,2,2.5,3]
[null,null,6,{"$f":"'CT Tables'!$D$7*E32","v":4.9005000000000001},9.8010000000000002,{"$f":"E32*'CT Tables'!$F$7","v":14.701499999999999},{"$f":"'CT Tables'!$G$7*E32","v":19.602},{"$f":"'CT Tables'!$H$7*E32","v":24.502500000000001},{"$f":"'CT Tables'!$I$7*E32","v":29.402999999999999},6,{"$f":"'CT Tables'!$D$7*L32","v":3.0510000000000002},6.1020000000000003,{"$f":"L32*'CT Tables'!$F$7","v":9.1530000000000005},{"$f":"'CT Tables'!$G$7*L32","v":12.204000000000001},{"$f":"'CT Tables'!$H$7*L32","v":15.255000000000001},{"$f":"'CT Tables'!$I$7*L32","v":18.306000000000001}]
[null,null,6.5,{"$f":"'CT Tables'!$D$7*E33","v":2.5114999999999998},5.0229999999999997,{"$f":"E33*'CT Tables'!$F$7","v":7.5344999999999995},{"$f":"'CT Tables'!$G$7*E33","v":10.045999999999999},{"$f":"'CT Tables'!$H$7*E33","v":12.557499999999999},{"$f":"'CT Tables'!$I$7*E33","v":15.068999999999999},6.5,{"$f":"'CT Tables'!$D$7*L33","v":1.5640000000000001},3.1280000000000001,{"$f":"L33*'CT Tables'!$F$7","v":4.6920000000000002},{"$f":"'CT Tables'!$G$7*L33","v":6.2560000000000002},{"$f":"'CT Tables'!$H$7*L33","v":7.82},{"$f":"'CT Tables'!$I$7*L33","v":9.3840000000000003}]
[null,null,7,{"$f":"'CT Tables'!$D$7*E34","v":1.7390000000000001},3.4780000000000002,{"$f":"E34*'CT Tables'!$F$7","v":5.2170000000000005},{"$f":"'CT Tables'!$G$7*E34","v":6.9560000000000004},{"$f":"'CT Tables'!$H$7*E34","v":8.6950000000000003},{"$f":"'CT Tables'!$I$7*E34","v":10.434000000000001},7,{"$f":"'CT Tables'!$D$7*L34","v":1.083},2.1659999999999999,{"$f":"L34*'CT Tables'!$F$7","v":3.2489999999999997},{"$f":"'CT Tables'!$G$7*L34","v":4.3319999999999999},{"$f":"'CT Tables'!$H$7*L34","v":5.415},{"$f":"'CT Tables'!$I$7*L34","v":6.4979999999999993}]
[null,null,7.5,{"$f":"'CT Tables'!$D$7*E35","v":1.984},3.968,{"$f":"E35*'CT Tables'!$F$7","v":5.952},{"$f":"'CT Tables'!$G$7*E35","v":7.9359999999999999},{"$f":"'CT Tables'!$H$7*E35","v":9.92},{"$f":"'CT Tables'!$I$7*E35","v":11.904},7.5,{"$f":"'CT Tables'!$D$7*L35","v":1.2355},2.4710000000000001,{"$f":"L35*'CT Tables'!$F$7","v":3.7065000000000001},{"$f":"'CT Tables'!$G$7*L35","v":4.9420000000000002},{"$f":"'CT Tables'!$H$7*L35","v":6.1775000000000002},{"$f":"'CT Tables'!$I$7*L35","v":7.4130000000000003}]
[null,null,8,{"$f":"'CT Tables'!$D$7*E36","v":4.024},8.048,{"$f":"E36*'CT Tables'!$F$7","v":12.071999999999999},{"$f":"'CT Tables'!$G$7*E36","v":16.096},{"$f":"'CT Tables'!$H$7*E36","v":20.12},{"$f":"'CT Tables'!$I$7*E36","v":24.143999999999998},8,{"$f":"'CT Tables'!$D$7*L36","v":2.5049999999999999},5.01,{"$f":"L36*'CT Tables'!$F$7","v":7.5149999999999997},{"$f":"'CT Tables'!$G$7*L36","v":10.02},{"$f":"'CT Tables'!$H$7*L36","v":12.524999999999999},{"$f":"'CT Tables'!$I$7*L36","v":15.03}]
[null,null,8.5,{"$f":"'CT Tables'!$D$7*E37","v":12.702500000000001},25.405000000000001,{"$f":"E37*'CT Tables'!$F$7","v":38.107500000000002},{"$f":"'CT Tables'!$G$7*E37","v":50.81},{"$f":"'CT Tables'!$H$7*E37","v":63.512500000000003},{"$f":"'CT Tables'!$I$7*E37","v":76.215000000000003},8.5,{"$f":"'CT Tables'!$D$7*L37","v":7.91},15.82,{"$f":"L37*'CT Tables'!$F$7","v":23.73},{"$f":"'CT Tables'!$G$7*L37","v":31.64},{"$f":"'CT Tables'!$H$7*L37","v":39.549999999999997},{"$f":"'CT Tables'!$I$7*L37","v":47.46}]
[null,null,9,{"$f":"'CT Tables'!$D$7*E38","v":40.618499999999997},81.236999999999995,{"$f":"E38*'CT Tables'!$F$7","v":121.85549999999999},{"$f":"'CT Tables'!$G$7*E38","v":162.47399999999999},{"$f":"'CT Tables'!$H$7*E38","v":203.09249999999997},{"$f":"'CT Tables'!$I$7*E38","v":243.71099999999998},9,{"$f":"'CT Tables'!$D$7*L38","v":25.265000000000001},50.53,{"$f":"L38*'CT Tables'!$F$7","v":75.795000000000002},{"$f":"'CT Tables'!$G$7*L38","v":101.06},{"$f":"'CT Tables'!$H$7*L38","v":126.325},{"$f":"'CT Tables'!$I$7*L38","v":151.59}]
[null,null,null,"Temperature: 15 oC",null,null,null,null,null,null,"Temperature: 25 oC"]
[null,null,null,"Log Reduction of Cylindrospermospsin",null,null,null,null,null," ","Log Reduction of Cylindrospermospsin"]
[null,null,"pH",0.5,1,1.5,2,2.5,3,"pH",0.5,1,1.5,2,2.5,3]
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[null,null,null,"Temperature: 30 oC"]
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[]
[]
[null,"References"]
[null,"Water Research 39 (2005) 1628 - 1638"]
[null,"Kinetics of reactions between chlorine and the cyanobacterial toxins microcystins"]
[null,"Juan L. Acero, Eva Rodriguez, Jussi Meriluoto"]
[]
[null,"Water Research 41 (2007) 2048 - 2056"]
[null,"Kinetics of oxidation of cylindrospemospsin and anatoxin-a with chlorine, monochloramine and permanganate"]
[null,"Eva Rodriguez, Ana Sordo, James S. Metcalf, Juan L. Acero"]

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[null,null,"Temp: 20 oC"]
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[null,"K6",5,null,5.95,null,6.78,null,7.74]
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[null,"K4",{"$f":"2.07*10^7","v":20700000}]
[null,"K5",{"$f":"3.152*'Cyanotoxin-Calc'!C8+53.74","v":101.02000000000001}]
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