Perchlorate in Drinking Water
The Division of Drinking Water (DDW), at a July 5, 2017 public hearing, presented to the State Water Board its findings and recommendations related to DDW's review of the perchlorate maximum contaminant level (MCL). DDW's recommendations (see the Perchlorate Review Public Document) were to first establish a lower detection limit for purposes of reporting (DLR) to gather additional occurrence data, and then revise the MCL, if the new data support development of a new standard.
The State Water Board approved DDW's proposal to investigate, develop, and propose revisions to the perchlorate DLR (see Resolution 2017-0041). DDW is currently exploring the feasibility of establishing a lower DLR for perchlorate.
Perchlorate and its salts are used in solid propellant for rockets, missiles, and fireworks, and elsewhere (e.g., production of matches, flares, pyrotechnics, ordnance, and explosives). Their use can lead to releases of perchlorate into the environment.
The California Department of Public Health (CDPH) – (via the Drinking Water Program, now the State Water Board, Division of Drinking Water) was mandated by §116293(b) of the Health and Safety Code to adopt a drinking water standard for perchlorate [maximum contaminant level (MCL)]. Health and Safety Code §116365 mandates that the MCL be set as close as possible to the public health goal (PHG), while considering cost and technical feasibility. The PHG is the concentration of a drinking water contaminant that does not pose a significant risk to human health if ingested in drinking water, established by Cal/EPA's Office of Environmental Health Hazard Assessment (OEHHA).
In 2004, OEHHA adopted a PHG of 0.006 mg/L (6 ppb) for perchlorate. Pursuant to the statutory mandates, the perchlorate MCL was established at 6 ppb with a detection level for purposes of reporting (DLR) of 4 ppb, and became effective October 2007. The regulation established monitoring requirements for determining public water system compliance with the MCL, and identified the appropriate analytical method for detecting perchlorate in drinking water, and "best available technologies" (BATs) for remediating perchlorate.
Health and Safety Code §116365(g) requires the State Water Board, at least once every five years, to review its MCLs. In the review, the State Water Board's MCLs are to be consistent with criteria of §116365(a) and (b). Those criteria state that the MCLs cannot be less stringent than federal MCLs, and must be as close as is technically and economically feasible to the PHGs established by the OEHHA. Consistent with those criteria, the State Water Board is to amend any standard if any of the following occur: (1) Changes in technology or treatment techniques that permit a materially greater protection of public health or attainment of the PHG, or (2) New scientific evidence indicates that the substance may present a materially different risk to public health than was previously determined. Each year by March 1, the State Water Board is to identify each MCL it intends to review that year.
In 2015, OEHHA revised the PHG for perchlorate from 6 ppb to 1 ppb. The revised PHG prompted the review of the perchlorate MCL.
Health Concerns and Public Health Safety
Perchlorate's interference with iodide uptake by the thyroid gland can decrease production of thyroid hormone, which is needed for prenatal and postnatal growth and development, as well as for normal metabolism and mental function in the adult.
Its effects on the thyroid gland are the basis of the 1-μg/L (PHG) established in 2015 by OEHHA. The 2015 PHG supersedes the 6-μg/L value established in 2004.
Perchlorate is regulated as an acutely toxic substance to reflect concerns about its potential for effects on the developing young. As a result, when a drinking water sample analyzed for perchlorate is found to exceed the MCL, regulations require the laboratory to quickly notify the water system of the findings, and public water systems must perform timely confirmation resampling and analysis. Also expedited is notification to DDW and to the public to help protect public health.
Laboratory Information: Alternative Analytical Methods
Most laboratories are using US Environmental Protection Agency (US EPA) Method 314 to detect perchlorate in drinking water. Method 314 is capable of satisfying the current DLR of 4 ppb for perchlorate. There are newer US EPA approved methods (e.g., US EPA Methods 331, 332, 314.1, and 314.2) that some labs are already using that may allow for a lower DLR.
Monitoring of perchlorate began in 1997, and showed perchlorate to be a widespread drinking water contaminant, occurring in several hundred wells, mostly in southern California (see history). Perchlorate was also found in the Colorado River, an important source of water for drinking and irrigation, where its presence resulted from contamination from ammonium perchlorate manufacturing facilities in Nevada.
The perchlorate MCL review process was based on water quality monitoring results collected from January 2013 to December 2016 from DDW's database (available here). The review was based on perchlorate findings from active and standby drinking water sources that had two or more reported detections at or greater than the DLR.
The current DLR of 4 μg/l limits DDW's ability to determine perchlorate in wells at lower concentrations (i.e., between 1 and 4 μg/L) because laboratories typically only report results down to the DLR. The DLR also limits DDW's ability to fully evaluate how various installed treatment technologies perform at removing perchlorate to values below 4 μg/L.
Customers interested in the quality of their drinking water should contact their water system or use the public drinking water watch portal at:
Correspondence with Water Systems about the Perchlorate MCL
Information and Contacts for Public Water Systems
Early Perchlorate Findings in Drinking Water
Other State and Federal Agencies' Perchlorate Information